The "Big Book" is a thought experiment developed by Ludwig Wittgenstein about the nature of ethics and the verifiability of ethical knowledge.
Wittgenstein's thought experiment goes as follows: Suppose there were an omniscient being who knew the position and movements of all of the physical bodies in the world (i.e. all of the natural properties of the world). Suppose further that this omniscient being wrote all of these natural facts in a large book, such that the book contained a thorough and comprehensive description of all of the things in the world. Wittgenstein argues that nothing in this book would even reference the idea of ethics or contain any statement that could logically be construed to imply an ethical judgment. His conclusion is that the concept of a moral fact is nonsensical, since even if one were to know every fact concerning the world that person still would not know anything factual about the realm of ethics.
"No statement of fact can ever be, or imply, a judgment of absolute value. Suppose one of you were an omniscient person and therefore knew all the movements of all the bodies in the world dead or alive and that you also knew all the states of mind of all human beings that ever lived, and suppose you wrote all you knew in a big book, then this book would contain the whole description of the world; and what I want to say is, that this book would contain nothing that we would call an ethical judgment or anything that would logically imply such a judgment."[1]